解决办法：
执行以下命令，删除mysql-libs-5.1.71-1.el6.x86_64：
yum -y remove mysql-libs-5.1.71*
再执行以下命令安装MySQL：
rpm -ivh MySQL-server-5.6.19-1.linux_glibc2.5.x86_64.rpm
一切Ok，安装成功了。
CentOS安装mysql*.rpm提示conflictswithfilefrompackage的解决办法(三)
.xml from install of MySQL-server-5.6.19-1.linux_glibc2.5.x86_64 conflicts with file from package mysql-libs-5.1.71-1.el6.x86_64
file /usr/share/mysql/charsets/hebrew.xml from install of MySQL-server-5.6.19-1.linux_glibc2.5.x86_64 conflicts with file from package mysql-libs-5.1.71-1.el6.x86_64
file /usr/share/mysql/charsets/hp8.xml from install of MySQL-server-5.6.19-1.linux_glibc2.5.x86_64 conflicts with file from package mysql-libs-5.1.71-1.el6.x86_64
file /usr/share/mysql/charsets/keybcs2.xml from install of MySQL-server-5.6.19-1.linux_glibc2.5.x86_64 conflicts with file from package mysql-libs-5.1.71-1.el6.x86_64
file /usr/share/mysql/charsets/koi8r.xml from install of MySQL-server-5.6.19-1.linux_glibc2.5.x86_64 conflicts with file from package mysql-libs-5.1.71-1.el6.x86_64
file /usr/share/mysql/charsets/koi8u.xml from install of MySQL-server-5.6.19-1.linux_glibc2.5.x86_64 conflicts with file from package mysql-libs-5.1.71-1.el6.x86_64
file /usr/share/mysql/charsets/latin1.xml from install of MySQL-server-5.6.19-1.linux_glibc2.5.x86_64 conflicts with file from package mysql-libs-5.1.71-1.el6.x86_64
file /usr/share/mysql/charsets/latin2.xml from install of MySQL-server-5.6.19-1.linux_glibc2.5.x86_64 conflicts with file from package mysql-libs-5.1.71-1.el6.x86_64
file /usr/share/mysql/charsets/latin5.xml from install of MySQL-server-5.6.19-1.linux_glibc2.5.x86_64 conflicts with file from package mysql-libs-5.1.71-1.el6.x86_64
file /usr/share/mysql/charsets/latin7.xml from install of MySQL-server-5.6.19-1.linux_glibc2.5.x86_64 conflicts with file from package mysql-libs-5.1.71-1.el6.x86_64
file /usr/share/mysql/charsets/macce.xml from install of MySQL-server-5.6.19-1.linux_glibc2.5.x86_64 conflicts with file from package mysql-libs-5.1.71-1.el6.x86_64
file /usr/share/mysql/charsets/macroman.xml from install of MySQL-server-5.6.19-1.linux_glibc2.5.x86_64 conflicts with file from package mysql-libs-5.1.71-1.el6.x86_64
file /usr/share/mysql/charsets/swe7.xml from install of MySQL-server-5.6.19-1.linux_glibc2.5.x86_64 conflicts with file from package mysql-libs-5.1.71-1.el6.x86_64 看到“conflicts”，是产生冲突了，文件“/usr/share/mysql/charsets/*”需要MySQL-server-5.6.19-1.linux_glibc2.5.x86_64版本的，而
系统已经存在mysql-libs-5.1.71-1.el6.x86_64版本的！